Cap the single long run, lean on back-to-backs
There is no single magic long run that "unlocks" 100 miles. Most coaches cap the longest single effort around 30 to 35 miles, because past that your body stops adapting and the recovery cost balloons. The far better tool is the back-to-back long run: a big effort on Saturday (say 25 to 30 miles) and then a moderate one on Sunday (15 to 20 miles). Running the second day on tired, glycogen-depleted legs is about as close as you can get to mile 70 of your race, including how your stomach acts when you are already cooked.
Build it in order. Stack your back-to-backs through the specific block, peak your biggest weekend roughly 4 to 5 weeks out, then taper. And resist the urge to cram one giant run into the last 3 weeks. It will not add fitness in time, and it can leave you flat or hurt on race day.